联系方式:
Email: liuqiuhua@hnust.edu.cn
主持的科研项目:
[1] 国家自然科学基金青年项目,大环变形对卟啉中心钴(Ⅱ)离子电子结构的调控(No. 21602054),20万,2017.01-2019.12
[2] 理论有机化学与功能分子教育部重点实验室开放基金,单氧杂核修饰卟啉对低价铜(I)离子的电荷效应(No.E21509),1.5万,2015.01-2016.12
[3] 新葡萄8883官网AMG博士科研启动基金,碳杂核修饰卟啉对高价钴(III)离子的电荷效应(No. E51777),3.0万,2017.03-2020.03
发表的主要论文:
[1] Liu, Q. H.; Zhou, X. C.; Liu, H. M.; Zhang, X.; Zhou, Z. C.* Fractional transfer of a free unpaired electron to overcome energy barriers in the formation of Fe4+ from Fe3+ during the core contraction of macrocycles. Org. Biomol. Chem. 2015, 13, 2939–2946.
[2] Liu, Q. H.; Zhang, X.; Zeng, W. N.; Wang, J. X.*; Zhou, Z. C.* Fine-tuning of electronic structure of cobalt(II) ion in nonplanar porphyrins and tracking of a cross-hybrid stage. J. Phys. Chem. B. 2015, 119, 14102–14110.
[3] Liu, Q. H.; Tang, M.; Zeng, W. N.; Zhang, X.; Wang, J. X.*; Zhou, Z. C.* Optimal size matching and minimal distortion energy. Eur. J. Inorg. Chem. 2016, 2016, 5222–5229.
[4] Liu, Q. H.; Zhang, X.; Zeng, W. N.; Wang, J. X.*; Zhou, Z. C.* Origin of d-π interaction in cobalt(II) porphyrins under synergistic effects of core contraction and axial ligation. Chin. J. Chem. 2016, 34, 910–918.
[5] Zhou, Z. C.*; Tang, M.; Liu, Q. H.*; Zhang, X. ; Zhou, X. C. Formation of π-cation radical in highly deformed copper(II) porphyrins. Eur. J. Inorg. Chem. 2016, 2016, 3585–3591.
[6] Zhou, Z. C.*; Zhou, X. C.; Liu, Q. H.*; Zhang, X.; Liu, H. M. Fixation of zinc(II) ion to dioxygen in a highly deformed porphyrin. Org. Lett. 2015, 17, 4078–4081.
[7] Zhou, Z. C.*; Zhang, X.; Liu, Q. H.*; Yan, Z. Q.; Lv, C. J.; Long, G. Geometry and temperature dependence of meso-aryl rotation in strained metalloporphyrins. Inorg. Chem. 2013, 52, 10258–10263.
[8] Zhou, Z. C.*; Liu, Q. H.; Yan, Z. Q.; Long, G.; Zhang, X.; Cao, C. Z.*; Jiang, R. Q. Conversion of electron configuration of iron ion through core contraction of porphyrin. Org. Lett. 2013, 15, 606–609.